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Question

When aromatic hydrocarbons are treated with chloroform and aluminum chloride, orange to red colours are obtained. These colours are due to the formation of triarylmethane, Ar3CH.

A
True
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B
False
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Solution

The correct option is A True
When aromatic hydrocarbons are treated with chloroform and aluminum chloride, orange to red colours are obtained. These colours are due to the formation of triarylmethyl cations, Ar3C+ which are formed by a Friedel-Craft reaction followed by a transfer of hydride ion.

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