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Question

When both N and S are present in an organic compound, what colour does the sodium extract with FeCl3 give?

A
Green
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B
Blue
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C
Yellow
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D
Red
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Solution

The correct option is D Red
Sodium fusion extract is used to detect the presence of elements like S, N, Cl, Br and I
If both N and S are present in organic compound then oragnic compound reacts with sodium fusion extract as follows:
Na+S+C+NNaSCN
This thiocyanate, SCN reacts with Fe3+ to give a blood red colouration due to formation of [Fe(SCN)]2+.
Fe3++SCN[Fe(SCN)]2+
(Red)
Hence, option d is correct.

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