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Question

When Br2 is passed into hot aqueous solution of Na2CO3 :

A
Br is formed by reduction
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B
BrO3 is formed by oxidation
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C
CO2 is evolved
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D
all of the above are correct
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Solution

The correct option is D all of the above are correct
First carbonate reacts with water and forms unstable acid which on dissociation gives CO2.
Na2CO3+H2O2NaOH+H2CO3
H2CO3H2O+CO2
The formed NaOH reacts with bromine and auto redox happens.
6NaOH+Br25NaBrbyreduction+NaBrO3byoxidation+3H2O
0 -1 +5

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