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Arrhenius Acid

When chlorofo...

Question

When chloroform is treated with excess oxygen it forms

A

C O C l_{2} + H C l

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B

C O C l_{2} + C l_{2} + H_{2}

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C

C O C l_{2} + C l_{2} + H_{2} O

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D

No product will be formed

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Solution

The correct option is B $C O C l_{2} + C l_{2} + H_{2} O$
$C H C l_{3} + O_{2} h v ⟶ C O C l_{2} + C l_{2} + H_{2} O$

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500

ml capacity vessel

C O

C l_{2}

are mixed to form

C O C l_{2}

at equilibrium, it contains

0.2

C O C l_{2}

0.1

C O

C l_{2}

. The equilibrium constant

K_{c}

C O + C l_{2} \Leftrightarrow C O C l_{2}

500

ml capacity vessel

C O

C l_{2}

are mixed to form

C O C l_{2}

at equilibrium, it contains 0.2 moles of

C O C l_{2}

and 0.1 mole each of

C O

C l_{2}

. The equilibrium constant

K_{c}

C O + C l_{2} ⇋ C O C l_{2}

500 m L

capacity vessel

C O

{C l}_{2}

are mixed to form

C O {C l}_{2}

. At equilibrium, it contains

0.2

C O {C l}_{2}

0.1

mole of each of

C O

{C l}_{2}

. The equilibrium constant

K_{c}

C O + {C l}_{2} ⇌ C O {C l}_{2}

C H_{3} C H_{2} N H_{2}

is treated with excess of

C O C l_{2}

to get the compound [A].

C O C l_{2}

is then treated with excess of

C H_{3} C H_{2} N H_{2}

to get the compound [B]. [A] and [B] respectively are :

Q. For the formation of phosgene from

C O (g)

C O (g) + {C l}_{2} (g) ⟶ C O {C l}_{2} (g)

, the experimentally determined rate equation is,

\frac{d [C O {C l}_{2}]}{d t} = k [C O] {[{C l}_{2}]}^{3 / 2}

.
Is the following mechanism consistent with the rate equation?

(i)

{C l}_{2} ⇌ 2 C l

(i i)

C l + C O ⇌ C O C l

(i i i)

C O C l + {C l}_{2} ⇌ C O {C l}_{2} + C l

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