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Question

When Cl2 gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from:

A
Zero to 1 and zero to +3
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B
Zero to +1 and zero to 3
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C
Zero to +1 and zero to 5
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D
Zero to 1 and zero to +5
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Solution

The correct option is D Zero to 1 and zero to +5
The reaction of chlorine gas with hot and concentrated sodium hydroxide solution is

3Cl2+6NaOHNaClO3+5NaCl+3H2O

Oxidation number of Cl is 0 in Cl2, 1 in NaCl and +5 in NaClO3

So the oxidation number of chlorine changes from Zero to -1 and Zero to +5.

Hence, the correct option is D

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