The reaction between Cu2+ ion and KI will take place as:
2Cu2+(aq)+4I−(aq)→Cu2I2(s)+I2white precipitate
In the aqueous solution, KI dissociates to give K+ and I−.
Since iodide ion (I−) is a strong reducing
agent, it reduces Cu2+ to Cu+and a white precipitate of Cu2I2 is formed.