When do I use the formula MV =M1V1-M2V2 and NV\:= N1V1-N2V2

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What is M1V1=M2V2 different from M1=M2V2/(V1+V2)and N1V1=N2V2

N_{1} V_{1} = N_{2} V_{2}

M_{1} V_{1} = M_{2} V_{2}

Column A	Column B
a) Force	i) $M a s s \times v e l o c i t y$
b) Law of conservation of momentum	ii) $M a s s \times a c c e l e r a t i o n$
c) Momentum	iii) $m_{1} v_{1} + m_{2} v_{2} = m_{1} u_{1} + m_{1} u_{1}$

When do we use the formula delta G=-nFE. and when do we use E=E⁰-0.059/nlogKc?

Are there any specific conditions for using these two?

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