When electrolysis of KCl is done in alkaline medium, 10 g of KClO3 is produced as follows : Cl⊖+6⊖OH→ClO⊖3+3H2O+6e− A current of 2 A is passed for 10.941 hours. The current efficiency (in %) used in the process is (MwtofKClO3=122.5) :
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Solution
Let x% is the current efficiency of KClO3 = Number of Faradays. 10g122.5/6=2×x×10.941×3600100×96500 ∴ x = 60%