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Question

When equal volumes of the following solutions are mixed, the precipitation of AgCl(Ksp=1.8×1010) will occur only with

A
104M(Ag) and 104M(Cl)
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B
105M(Ag) and 105M(Cl)
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C
106M(Ag) and 106M(Cl)
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D
1010M(Ag) and 1010M(Cl)
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Solution

The correct option is A 104M(Ag) and 104M(Cl)
Precipitation will occur when
ionic product of AgCl> solubility product of AgCl

104M(Ag) and 104M(Cl) present.

Here, [Ag+][Cl]=1042×1042=2.5×109>Ksp

So precipitation will occur.

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