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Question

When ethanol is converted to ethanoic acid by using acidified potassium dichromate, the ethanol is:

A
reduced and the colour changes from orange to green
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B
reduced and the colour changes from green to orange
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C
oxidised and the colour changes from orange to green
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D
oxidised and the colour changes from green to orange
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Solution

The correct option is C oxidised and the colour changes from orange to green
(ethanol)C2H5OH+[O]CH3CHO+H2O
CH3CHO+[O]CH3COOH
(ethanoic acid)
This reaction takes place in presence of strong oxidizing agents like K2Cr2O7+(dil.)H2SO4
K2Cr2O7orange+4H2SO4(dil.)K2SO4+Cr(SO4)3green+4H2O+3[O]
This reaction takes place underneath, which provides nascent oxygen. Due to this, color changes from orange to green.

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