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Question

When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives:

A
2-Chloropropane
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B
Allyl chloride
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C
No reaction
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D
n-propyl chloride
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Solution

The correct option is A 2-Chloropropane
Peroxide effect is observed only in case of HBr.

With HCl, even in the presence of peroxides, only Markovnikov's product, i.e., 2-Chloropropane is obtained.

Option A is correct.

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