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Question

When is Hα line in the emission spectrum of hydrogen atom obtained? Calculate the frequency of the photon emitted during this transition.

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Solution

Energy of an electron in the nth orbit hydrogen atom is given by ,
En=13.6/n2eV
Hα line in the emission spectrum of hydrogen atom is obtained in 32 transition.
Frequency of photon obtained in the transition is given by:
ΔE=hf=13.6(1914) eV
ΔE=13.6×536×1.6×1019 J
f=ΔEh=13.6×5×1.6×101936×6.6×1034
f=4.57×1014 Hz

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