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Question

When K4[Fe(CN)6] is treated with FeCl3, a blue color is obtained.


It is due to the formation of :

A
FeII[FeIII(CN)6]
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B
FeIII[FeII(CN)6]
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C
Both (a) and (b)
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D
None of these
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Solution

The correct option is C Both (a) and (b)
When K4[Fe(CN)6] is treated with FeCl3, a blue color is obtained.

It is due to the formation of FeII[FeIII(CN)6] and FeIII[FeII(CN)6].

4FeCl3+3K4[Fe(CN)6]Fe4[Fe(CN)6]3+12KCl

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