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Byju's Answer
Standard X
Chemistry
Chemical Equilibrium in Reversible Reactions
When K4[FeC...
Question
When
K
4
[
F
e
(
C
N
)
6
]
is treated with
F
e
C
l
3
, a blue color is obtained.
It is due to the formation of :
A
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
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B
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
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C
Both (a) and (b)
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D
None of these
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Solution
The correct option is
C
Both (a) and (b)
When
K
4
[
F
e
(
C
N
)
6
]
is treated with
F
e
C
l
3
, a blue color is obtained.
It is due to the formation of
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
and
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
.
4
F
e
C
l
3
+
3
K
4
[
F
e
(
C
N
)
6
]
→
F
e
4
[
F
e
(
C
N
)
6
]
3
+
12
K
C
l
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0
Similar questions
Q.
Select correct statement(s):
I) When excess
F
e
C
l
3
solution is added to
K
4
[
F
e
(
C
N
)
5
]
solution, in addition to
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
,
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
is also formed due to side redox reaction
(II) When
F
e
C
l
2
is added to
K
3
[
F
e
(
C
N
)
6
]
solution, in addition to
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
,
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
is also formed due to side redox reaction
(III)
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
is paramagnetic while
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
is diamagnetic
(IV)
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
is diamagnetic while
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
,
is paramagnetic
Q.
Turnbull's blue and Prussian's blue respectively are
:
(I).
F
e
I
I
[
F
e
I
I
(
C
N
)
6
]
2
−
(II).
F
e
I
I
I
[
F
e
I
I
I
(
C
N
)
6
]
(III).
F
e
I
I
[
F
e
I
I
I
(
C
N
)
6
]
−
(IV).
F
e
I
I
I
[
F
e
I
I
(
C
N
)
6
]
−
Q.
When
F
e
C
l
3
is treated with
K
4
[
F
e
(
C
N
)
6
]
, a blue coloured compound is formed. What are the total number of atoms per formula molecule? (supposing no K is present in blue coloured compound)
Q.
Ferric ion forms a Prussian blue coloured precipitate with
K
4
[
F
e
(
C
N
)
6
]
due to the formation of :
Q.
F
e
C
l
3
on reaction with
K
4
[
F
e
(
C
N
)
6
]
in aqueous solution gives blue colour. These are separated by a semipermeable membrane AB as shown. Due to osmosis, there is:
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