When KMnO4 acts as an oxidizing agent and ultimately formsMnO−24 ,MnO2 ,Mn2O3 andMn+2 , then the number of electrons transferred ( per Mn atom) in each case respectively is:
1, 3, 4, 5
Check the oxidation states of Mn.
⟹ No of electrons transferred will be change in oxidation state
+7MnO−4+e−⟶+6MnO−24
+7MnO−4+3e−⟶+4MnO2
+7MnO−4+4e−⟶+3Mn2O3;
+7MnO−4+5e−⟶+2Mn2+