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Question

When mercuric iodide is added to an aqueous solution of KI then:

A
boiling point increase
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B
boiling point decrease
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C
freezing point increase
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D
osmotic pressure increase
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Solution

The correct option is C freezing point increase
Freezing point of the solution will increase
HgI2+2KIK2[HgI4]
This association will decrease the number of ions. As a result Vant Hoff factor (i) will decrease. Now freezing point depression ΔT=iKfm
As depression is decreased, freezing point is increased.

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