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Standard XII
Chemistry
Elevation in Boiling Point
When mercuric...
Question
When mercuric iodide is added to an aqueous solution of
K
I
then:
A
boiling point increase
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B
boiling point decrease
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C
freezing point increase
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D
osmotic pressure increase
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Solution
The correct option is
C
freezing point increase
Freezing point of the solution will increase
H
g
I
2
+
2
K
I
⟶
K
2
[
H
g
I
4
]
This association will decrease the number of ions. As a result Vant Hoff factor (i) will decrease. Now freezing point depression
Δ
T
=
i
K
f
m
As depression is decreased, freezing point is increased.
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Similar questions
Q.
Assertion :When mercuric iodide is added to the aqueous solution of
K
I
, the freezing point is raised.
Reason:
H
g
I
2
reacts with
K
I
forming complex ion
[
H
g
I
4
]
2
−
.
Q.
What will happen to freezing point of a potassium iodide aqueous solution when mercuric Iodide as added to solution. Explain.
Q.
When mercuric iodide is added to an aqueous solution of potassium iodide the:
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