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Question

When mercuric iodide is added to aqueous KI solution:

A
Freezing point is raised
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B
Osmotic pressure is raised
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C
Boiling point is elevated
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D
Vapour pressure is raised
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Solution

The correct option is A Freezing point is raised
When HgI2 is added to KI, a complex is formed.
HgI2+2KIK2[HgI4]
As the number of I particles decreases so freezing point increases.
Hence option A is correct.

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