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Question

When NaNO3 is heated in a closed vessel, oxygen is liberated and NaNO2 is left behind. Then at equilibrium:

A
addition of NaNO2 favours reverse reaction
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B
addition of NaNO2 favours forward reaction
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C
increasing temperature favours forward reaction
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D
decreasing pressure favours reverse reaction
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Solution

The correct options are
A addition of NaNO2 favours reverse reaction
C increasing temperature favours forward reaction
According to Le Chatlier's principle:

Increasing the concentration of product will shift the equilibrium backward, thus the addition of NaNO2 favours the reverse direction.

Increasing temperature favours the forward reaction as this is the endothermic direction.

2NaNO3(s)2NaNO2(s)+O2(g) (endothermic)

Also, decreasing pressure favours forward reaction.

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