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Question

When nitration of aniline occurs, ortho, meta and para nitro aniline is formed. Arrange them in the increasing order of their % yield.

A
o>m>p
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B
m>o>p
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C
p>o>m
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D
p>m>o
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Solution

The correct option is D p>m>o
Due to +R effect of NH2, only ortho and para products should be formed. But, in this case due to conversion of NH2 to NH+3 in presence of acidic medium, only –I effect is exerted on benzene ring. Hence, we get the maximum yield of para then meta and minimum yield for ortho product. Therefore, the correct order of yield is p>m>o

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