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Question

When nitrobenzene is reduced with a metal and acid (Sn/HCl, Zn/HCl etc.),
which of the following product(s) is obtained?

A
aniline
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B
nitrosobenzene
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C
phenylhydroxylamine
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D
all of the above
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Solution

The correct option is A aniline
When nitrobenzene is reduced with a metal and acid (Sn/HCl, Zn/HCl etc.), aniline is obtained. The intermediate products nitrosobenzene and phenylhydroxylamine are never isolated because these are reduced more rapidly than nitrobenzene.

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