When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have maximum kinetic energy (KE)A and de-Broglie wavelength is λA. The maximum kinetic energy of photoelectrons liberated from another metal B by photons of energy 4.7 eV is (KE)B, where (KE)B=(KE)A–1.5 eV. If the de-Broglie wavelength of these photoelectrons is λB(=2λA), then:
The work function of metal A is 2.25 eV
The work function of metal B is 4.20 eV
(KE)A=2ev
4.25=(W0)A+(K.E)A4.70=(W0)B+(K.E)A−1.5
So, (W0)B−(W0)A=0.45+1.5=1.95...(1)
Now, λB=2λA
h√2m(K.E.)B=2h√2m(K.E.)A
So, (K.E.)A=4(K.E.)B
4.25−(W0)A=4[4.7−(W0)B]
4(W0)B−(W0)A=14.55......(2)
On solving (1) and (2)
(W0)B=4.2eV
(W0)A=2.25eV
(K.E.)A=2eV
(K.E.)B=0.5eV