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Question

When potassium cyanide reacts with water, will the resulting solution be acidic, alkaline or neutral? Justify your answer.

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Solution

The resulting solution will be alkaline because KCN is a salt of strong base and weak acid. It undergoes anionic hydrolysis when dissolved in water.
KCN+HOHK++CN+H++OH
H++CNHCN (anionic hydrolysis).
HCN is a weak acid because it gives less H+ ions in the solution while KOH is strong electrolyte and remains completely dissociated.

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