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Question

When sodium acetate is added to an aqueous solution of acetic acid :

A
The pH of the solution decreases
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B
The pH of the solution increases
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C
The pH of the solution remains unchanged
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D
An acid salt is produced
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Solution

The correct option is B The pH of the solution increases
Dissociation of CH3COOH is suppressed by the addition of sodium acetate (CH3COONa) due to common ion (CH3COO) effect. The [H+] decreases raising the pH of the acid solution.
Note : After the addition of CH3COONa to CH3COOH, a buffer solution is formed which has reserved pH value.

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