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Question

When sodium is dissolved in lequid ammonia, a solution of deep blue colour is obtained. The colour of the solution is due to
(a) ammoniated electron (b) sodium ion
(c) sodium amide (d) ammoniated sodium ion

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Solution

Answer: (a) ammoniated electron

All alkali metal dissolves in liquid NH3 giving highly conducting deep blue solution,
Na+(x+y)NH3[Na(NH3)x]++e(NH3)yWhen light fall on these solutions the ammoniated electrons excite in higher energy level by absorbing red wavelengths and so transmitted light is blue.


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