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Question

When solution of sodium chloride containing ethyl alcohol is electrolysed, it finally forms :

A
chloral
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B
chloroform
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C
ethyl chloride
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D
acetaldehyde
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Solution

The correct option is A chloroform
Electrolysis of NaCl solution gives NaOH and Cl2 since the system contains ethyl alcohol, NaOH, and Cl2

Ethanol in presence of base and chlorine undergoes chloroform reaction,

CH3CH2OH+Cl2+NaOHHCOONa+CHCl3+5HCl

Option B is correct.

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