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Question

When solution of ZnS in dil.HCl is treated with NaOH solution, a white ppt. is formed which dissolves in excess of NaOH due to formation of :

A
ZnCl2
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B
Zn(OH)Cl
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C
Na2ZnO2
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D
None of these
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Solution

The correct option is C Na2ZnO2
Option (C) is correct.
When solution of ZnS in dil.HCl is treated with NaOH solution, a white ppt. is formed which dissolves in excess of NaOH due to formation of Na2ZnO2.
ZnS+2HClZnCl2+H2S
ZnCl2+2NaOHZn(OH)2+2NaCl
Zn(OH)2+2NaOHNa2ZnO2+2H2O(soluble)

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