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Question

When some NaCl was dissolved in water, the freezing point depression was numerically equal to twice the molal Kf depression constant. The relative lowering of vapour pressure of the solution is nearly:

A
0.036
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B
0.018
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C
0.0585
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D
0.072
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Solution

The correct option is A 0.036
ΔTf=KfW1M1×W2×1000 [W2 is given in grams]
where 1 and 2 denote solute & solvent respectively.
Given, ΔTf=2KfW1×1000M1×W2=2
Relative lowering of vapour pressure= W1×M2M1×W2
Here, M2= Molecular weight of H2O=18
Relative lowering of vapour pressure= (W1M1×W2)×18
=21000×18
=0.036

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