General Mechanism of Electrophilic Aromatic Substitution
When sulphoni...
Question
When sulphonilic acid (p−H2NC6H4SO3H) is treated with an excess of bromine, the product is:
A
tribromo product
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B
dibromo product
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C
monobromo product
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D
tetrebromo product
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Solution
The correct option is B dibromo product Amino group is ortho and para directing whereas sulphonic acid group is meta directing. When sulphonilic acid (p−H2NC6H4SO3H) is treated with excess of bromine, the product is dibromo product 4-amino-3,5-dibromobenzenesulfonic acid.