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Question

When sulphur dioxide is passed in an acidified K2Cr2O7 solution, the oxidation state of sulphur is changed from:

A
+4 to 0
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B
+4 to +2
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C
+4 to +6
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D
+6 to +4
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Solution

The correct option is C +4 to +6
Reaction of sulphur dioxide with K2Cr2O7 in acidic medium is given as:

3SO2+Cr2O27+2H+3SO24+2Cr3++H2O

Oxidation state of Sulphur in SO2 is +4 which changes to +6 in SO24.

Hence, option C is correct.

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