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Question

When tert-butylchloride is added to an equal amount of ethanol in an inert solvent, one of the products is ethyl tert-butyl ether. When the concentration of ethanol is doubled, the rate of the reaction:

A

drops alarmingly to a small fraction

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B

doubles

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C

remains constant

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D

halves

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Solution

The correct option is C

remains constant


This reaction of clearly SN1. The rate expression is:

Reaction rate=[tertbutylchloride]

Since the rate is independent of the concentration of ethanol, the rate remains constant provided the temperature is constant.


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