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Question

When the heat of reaction at constant pressure is 2.5×103 cal and entropy change is 7.4 cal deg1 at 25C, the reaction is predicted as:

A
reversible
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B
spontaneous
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C
non-spontaneous
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D
irreversible
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Solution

The correct option is C spontaneous
For the reaction at constant pressure,
H=2.5×103cal

S=7.4 cal deg1

G=HTS=2.5×103298×7.4

ΔG=2.5×1032205.2

G=4705.2 cal

Since ΔG is negative so the reaction is spontaneous.

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