When there are no external forces, the shape of a liquid drop is determined by
the surface tension of the liquid
When there are no external forces, the shape of a liquid drop is determined by the surface tension of the liquid. Surface tension acts in a way that it reduces the surface area of the liquid. For a given volume the surface area of a sphere is least.
Hence, when a drop of liquid is not under the influence of any external force they are spherical in shape.