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Question

When two equal size pieces of the same metal at different temperatures Th (hot piece) and Tc (cold piece) are brought into thermal contact and isolated from it's surrounding. The total change in entropy of system is given by__________.

A
Cvln(Tc+Th)24ThTc
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B
CvlnThTc
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C
Cvln(Tc+Th)22ThTc
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D
CvlnTc+Th2Tc
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Solution

The correct option is A Cvln(Tc+Th)24ThTc
For a small exchange in heat at time 't'. Change of entropy for hot piece=dqT1h
Where T1h is temp of hot piece at time 't'. Change of entropy for cold piece=dqT1c.
As heat capacities of the pieces is same.
Tc+Th=T1c+T1h=2Tf
Where Tf is final temperature of each piece.
ΔS for hot piece dqT1h=CvTfThdTT1h=CvlnTfTh
Similarly, ΔS for cold piece =CvlnTfTc (where Cv is the heat capacity of each body at constant volume).
TotalΔS=CvlnT2fThTc=Cvln(Tc+Th)24ThTc.

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