Which among the following combinations is maximum boiling azeotrope?

H_{2} O + C H_{3} O H

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C C l_{4} + C H C l_{3}

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(C H_{3})_{2} C O + C_{2} H_{5} O H

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H_{2} O + H N O_{3}

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Solution

The correct option is C $H_{2} O + H N O_{3}$
The maximum boiling azeotrope is shown when there is a negative deviation from Raoult's law.

So, it is $H_{2}$ O and $H N O_{3}$ mixture since mixture form strong intermolecular H-bonding.

Option D is correct.

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Similar questions

Q. Which among the following is a maximum boiling azeotrope?

Q. Which of the following combination shows maximum boiling azeotrope?

Q. Which of the following molecule/molecules will be have zero dipole moment?

H_{2} O, C O_{2}, C C l_{4}, C H C l_{3}, N H_{3}, B F_{3}, B e F_{2}

Q. Match the following

Column - I	Column - II
a) A nearly ideal solution	p) $H_{2} O + C_{2} H_{5} O H$
b) A solution showing positive deviation	q) $C_{6} H_{6} + C_{6} H_{5} C H_{3}$
c) A solution showing negative deviation	r) $C_{6} H_{6} + C H C l_{3}$
d) An azeotropic mixture	s) $C H_{3} C O C H_{3}$ + $C_{2} H_{5} O H$
	t) $Δ H$ and $Δ V$ are positive
	u) $Δ H$ and $Δ V$ are negative

The variation of vapour pressure (b) as a function of temperature (a) is studied for $C_{2} H_{5} O C_{2} H_{5}, C C l_{4}, a n d H_{2} O$ at 760mm Hg and is shown in the figure below. The boiling temperature of $C_{2} H_{5} O C_{2} H_{5}, C C l_{4}, a n d H_{2} O$ are 308,350 and 373K respectively. Curves A,B, C respectively correspond to:

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Which among the following combinations is maximum boiling azeotrope?

The correct option is C H2O+HNO3The maximum boiling azeotrope is shown when there is a negative deviation from Raoult's law. So, it is H2O and HNO3 mixture since mixture form strong intermolecular H-bonding. Option D is correct.

The correct option is C $H_{2} O + H N O_{3}$
The maximum boiling azeotrope is shown when there is a negative deviation from Raoult's law.

So, it is $H_{2}$ O and $H N O_{3}$ mixture since mixture form strong intermolecular H-bonding.

Option D is correct.