Which among the following molecules have $s p^{3} d$ hybridisation with one lone pair of electrons on the central atom ?
(i) $S F_{4}$ (ii) $[P C I_{4}]^{+}$ (iii) $X e O_{2} F_{2}$ (iv) $C l O F_{3}$

(i), (ii) and (iii) only

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(i), (iii) and (iv) only

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(i) and (ii) only

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(iii) and (iv) only

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Solution

The correct option is B (i), (iii) and (iv) only
In $S F_{4}$ , sulfur atom contains one lone pair of electron and has $s p^{3} d$ hybridisation.
In $X e O_{2} F_{2}$ , $X e$ atom contains one lone pair of electron and has $s p^{3} d$ hybridisation.
In $C l O F_{3}$ , $C l$ atom contain one lone pair of electron and has $s p^{3} d$ hybridisation.
So answer is B.

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