Which among the following represents the correct decreasing order of acidic strength for the following compounds?
A
I>II>III>IV
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B
II>III>I>IV
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C
IV>III>I>II
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D
III>II>IV>I
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Solution
The correct option is BII>III>I>IV (II) is the most acidic due to ortho effect. (IV) is least acidic since +R effect of OH group is more pronounced over its -I effect. (III) is more acidic than (I) as -I effect of OH stabilised the conjugate base.