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Question

Which compound has planar structure?

A
XeF4
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B
XeOF2
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C
XeO2F2
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D
XeO4
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Solution

The correct option is C XeF4
In XeF4 molecule, central atom Xe has 6 electron pairs around it in which 4 electron pairs are bonding pairs and 2 electron pairs are lone pairs.
As 6 electron pairs are three XeF4 structure should be octahedral but it square planar due to two lone pairs on it.
Because of two lone pairs repulsions increases and shape becomes square planar.

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