Which compound is soluble in water :

{[{(C H_{3})}_{2} N H_{2}]}_{2}^{+} C l^{-}

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{[C H_{3} N H_{3}]}_{3}^{+} C l^{-}

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{[{(C H_{3})}_{3} N H]}_{3}^{+} C l^{-}

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P h N O_{2}

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Solution

The correct options are
A ${[C H_{3} N H_{3}]}_{3}^{+} C l^{-}$
C ${[{(C H_{3})}_{3} N H]}_{3}^{+} C l^{-}$
D ${[{(C H_{3})}_{2} N H_{2}]}_{2}^{+} C l^{-}$
Nitro benzene is insoluble in water.
Mono, di, tri and tetra alkyl ammonium halides are soluble in water.
Thus ${[{(C H_{3})}_{2} N H_{2}]}_{2}^{+} C l^{-}, {[C H_{3} N H_{3}]}_{3}^{+} C l^{-} a n d {[{(C H_{3})}_{3} N H]}_{3}^{+} C l^{-}$ are soluble in water.

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