The correct option is D 4th electron
After removing the 1st electron, the energy required to remove the 2nd electron from its orbit is higher than that of the 1st electron.
This is because 6 protons now attract 5 electrons and they exert more force on them compared to the previous case.
Similarly, energy to remove the 4th electron >>> energy to remove the 3rd electron >> energy to remove the 2nd electron.