The correct option is B B
s-orbital is spherical in shape so the electrons present in s-orbital will have spherical eletron density.
Option(a)
Electronic configuration of He : 1s2 (spherical eletron density)
Option(b)
Electronic configuration of B : 1s22s22p1
B has electron in p-orbital so it can contain non-spherical electron density as well.
Option(c)
Electronic configuration of Be : 1s22s2 (spherical electron density)
Option(d)
Electronic configuration of Li : 1s22s1 (spherical electron density)
Hence, the correct option is (b).