Which element in the square brackets has the highest oxidation number among the given options?
K2[Cr2]O7
Let's calculate the oxidation number for all the options given to us.
(1) For H2[C]O3, let oxidation number of C be x.
Oxidation numbers of H and O are +1 and -2 respectively
+2+x+3×(−2)=0
Hence, the oxidation number of C = +4.
(2) For [Mg]Cl2, let oxidation number of Mg be x.
Oxidation number of Cl is -1.
x+2×(−1)=0
Hence, the oxidation number of Mg = +2.
(3) For H3[P]O4, let oxidation number of P be x.
Oxidation numbers of H and O are +1 and -2 respectively.
3×(+1)+x+4×(−2)=0
Hence, the oxidation number of P = +5.
(4) For K2[Cr2]O7, let oxidation number of Cr be x.
Oxidation numbers of K and O are +1 and -2 respectively
2×(+1)+2×x+7×(−2)=0
Hence, the oxidation number of Cr = +6.
So the highest oxidation is of Cr element among the given options which is equal to +6.