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Question

Which gives maximum yield of C2H5Cl?

A
C2H6+Cl2excesshv.light−−−C2H5Cl+HCl
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B
C2H6excess+Cl2hvlightC2H5Cl+HCl
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C
C2H6+Cl2hvlightC2H5Cl
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D
C2H6+Cl2Dark−−C2H5Cl+HCl
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Solution

The correct option is B C2H6excess+Cl2hvlightC2H5Cl+HCl
The reaction of C2H6 and Cl2 in presence of hν light can give monochlorination as well as di and tri chlorination.
If we want the only monochlorinated product, we need to make sure that Cl2 is used for monochlorination only. This is possible when C2H6 is taken in excess.

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