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B
C2H6excess+Cl2hv−−→lightC2H5Cl+HCl
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C
C2H6+Cl2hv−−→lightC2H5Cl
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D
C2H6+Cl2Dark−−−→C2H5Cl+HCl
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Solution
The correct option is BC2H6excess+Cl2hv−−→lightC2H5Cl+HCl The reaction of C2H6 and Cl2 in presence of hν light can give monochlorination as well as di and tri− chlorination.
If we want the only monochlorinated product, we need to make sure that Cl2 is used for monochlorination only. This is possible when C2H6 is taken in excess.