The correct option is
B Na2CO3The acids have a pH lower than 7, the bases have a pH higher than 7 and neutral compounds have a pH 7.
NaNO3 is salt formed by the combination of a strong acid HNO3 and a strong base NaOH and hence it is neutral with a pH 7.
CH3COOK is a salt formed by the combination of weak acid CH3COOH and strong base KOH and hence on hydrolysis it's pH will be above 7 since it will be slightly basic.
NH4Cl is a salt formed by the formation of strong acid HCl and a weak base NH4OH and hence on hydrolysis it's pH will be lesser than 7 since it is slightly acidic nature.
Na2CO3 is a base and hence it's pH will be much greater than 7 and it will have the highest pH among the following compounds.
Hence, the correct answer is option (B).