Atomic mass of Na = 23 u (Given)
Then, gram atomic mass of Na = 23 gm
Now, 23 gm of Na Contains = 6.022 x 1023 number of atoms
Thus, 200 gm of Na contains =6.022×102323×200=52.36×1023 atoms
Now in the second case,
The atomic mass of Fe = 56 u (Given)
Then, the gram atomic mass of Fe = 56 gm
Now, 56 gm of Fe contains = 6.022 x 1023 number of atoms
Thus, 200 g of Fe contains =6.022×102356×200=21.5×1023 atoms
So, the number of atoms are more in 200 gm of Na than in 200 gm of Fe.