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Standard XII

Chemistry

Werner's Coordination Theory

which has the...

Question

which has the maximum conductivity in thier 0.1M solution?

[C o {(N H}_{3})_{3} {C l}_{3}]

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[C o ({N H}_{3})_{4} C l] {C l}_{2}

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[C o ({N H}_{3})_{5} C l] {C l}_{2}

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[C o ({N H}_{3})_{6}] {C l}_{3}

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Solution

The correct option is D D) $[C o ({N H}_{3})_{6}] {C l}_{3}$
The maximum conductivity is shown by that compound which have maximum ions on dissociation. Hence the compound $[C o (N H_{3})_{6}] C l_{3}$ have the maximum number of ions $[C o (N H_{3})_{6}] + 3 C l^{-}$ = 4 ions and hence the correct answer is D.

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Similar questions

Arrange the following complexes in the increasing order of conductivity of their solution

$[C o (N H_{3})_{3} C l_{3}], [C o (N H_{3})_{4} C l_{2}] C l, [C o (N H_{3})_{6}] C l_{3}, [C o (N H_{3})_{5} C l] C l_{2}$

Q. The correct order of the following complexes according to increasing conductivity of their solutions will be:
(i)

[C o (N H_{3})_{3} C l_{3}]

(ii)

[C o (N H_{3})_{4} C l_{2}] C l

(iii)

[C o (N H_{3})_{6}] C l_{3}

(iv)

[C o (N H_{3})_{5} C l] C l_{2}

Q. Among the following, which complex compound is diamagnetic?

[C o (N H_{3})_{6}] C l_{3}

,
ii)

[N i (N H_{3})_{6}] C l_{2}

,
iii)

[C r (H_{2} O)_{6}] C l_{3}

,
iv)

[F e (H_{2} O)_{6}] C l_{2}

Q. Among

(i) [C o (N H_{3})_{5}] C l_{3}, (i i) [N i (N H_{3})_{5}] C l_{2}, (i i i) [C r (H_{2} O)_{6}] C l_{3}, (i v) [F e (H_{2} O)_{6}] C l_{2}

the complex which is diamagnetic is :

Q. Among the following complexes, the diamagnetic complexes are:

(K) : K_{3} [F e (C N)_{6}]

(L) : [C o (N H_{3})_{6}] C l_{3}

(M) : N a_{3} [C o (o x a l a t e)_{3}]

(N) : [N i (H_{2} O)_{6}] C l_{2}

(O) : K_{2} [P t (C N)_{4}]

(P) : [Z n (H_{2} O)_{6}] (N O_{3})_{2}

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which has the maximum conductivity in thier 0.1M solution?

The correct option is D D) [Co(NH3)6]Cl3The maximum conductivity is shown by that compound which have maximum ions on dissociation. Hence the compound [Co(NH3)6]Cl3 have the maximum number of ions [Co(NH3)6]+3Cl− = 4 ions and hence the correct answer is D.