The correct option is A Li+→Li+2+e−
The second ionization potential of Li involves greatest amount of energy as it involves breaking of stable 1s2 electronic configuration.
Li+→Li2++e−
1s2→1s1
The second ionization of potassium, the first ionization of Fe and the second ionization of Ca requires removal of an electron from [Ar], 3d64s1 and 4s1 electronic configurations respectively.