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Byju's Answer
Standard XII
Chemistry
VBT vs CFT - Octahedral Complexes
Which is/are ...
Question
Which is/are used as ligand in complexes?
A
C
N
−
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B
C
O
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C
Both (A) and (B)
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D
None of these
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Solution
The correct option is
C
Both (A) and (B)
Both
C
O
and
C
N
−
have lone pair of electron for donation so they both can act as ligand.
N
i
+
4
C
O
→
N
i
(
C
O
)
4
N
i
+
4
C
N
−
→
N
i
(
C
N
)
2
−
4
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Similar questions
Q.
Both
[
N
i
(
C
O
)
4
]
and
[
N
i
(
C
N
)
4
]
2
−
are diamagnetic. The hybridizations of nickel in these complexes, respectively, are:
Q.
Both
[
N
i
(
C
O
)
4
]
and
[
N
i
(
C
N
)
4
]
2
−
are diamagnetic. The hybridisations of nickel in these complexes respectively are
Q.
Both
[
N
i
(
C
O
)
4
]
and
[
N
i
(
C
N
)
4
]
2
−
are diamagnetic. The types of hybridisation of
N
i
in these complexes are respectively:
Q.
C
r
3
+
form four complexes with four different ligands which are
[
C
r
(
C
l
)
6
]
3
−
,
[
C
r
(
H
2
O
)
6
]
3
+
,
[
C
r
(
N
H
3
)
6
]
3
+
and
[
C
r
(
C
N
)
6
]
3
−
. The order of CFSE
(
Δ
o
)
in these complexes is in the order
:
Q.
What is the total number of isomers including stereoisomers that have the formula
K
3
[
C
o
(
C
N
)
6
]
? (All are octahedral complexes with
C
o
3
+
and ambidentate ligand
C
N
−
)
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