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Question

Which is less acidic than phenol?

A
2,4,6-Trimethyl phenol
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B
CH3OH
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C
p-Nitrophenol
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D
H2O
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Solution

The correct options are
A 2,4,6-Trimethyl phenol
B CH3OH
D H2O
In 2,4,6trimethylphenol and CH3OH methyl groups exhibit +I effect and decrease acidity. In H2O hydrogen bonding makes hydrogen less available and less acidic. But in pnitrophenol the M effect of NO2 group makes it more acidic than phenol.


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