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Conformations of Butane

Which is more...

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Which is more stable among 2-methyaniline and 3-methylaniline? Why?

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(i) 3-Methylaniline into 3-nitrotoluene.

(ii) Aniline into 1,3,5-tribromobenzene.

Q. Give one chemical test to distinguish between Aniline and N-methylaniline.

Q. A mixture contains

4 -

2 -

3 -

chlorobenzoic acid and

1, 3 -

dinitrobenzene.
The following scheme of separation is used to separate its constituents.
The correct statement(s) regarding the separation method is/are:

Q. Aniline and N-methylaniline cannot be distinguished by azo dye test
If this is true enter 1, if false enter 0.

Q. (a) Illustrate the following reactions giving suitable example in each case :
(i) Hoffmann bromaimide degradation reaction
(ii) Diazotisation
(iii) Gabriel phthalimide synthesis

(b) Distinguish between the following pairs of compounds :
(i) Aniline and N-methylaniline

(i i) (C H_{3})_{2} N H

(C H_{3})_{3} N

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Conformations of Butane

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