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Question

Which is most volatile out of o-m and p-nitrophenol?

A
o-nitrophenol
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B
m-nitrophenol
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C
p-nitrophenol
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D
all the equally volatile
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Solution

The correct option is A o-nitrophenol

Ortho nitrophenol is more volatile than para and meta nitro phenol. It is due to the presence of Intramolecular Hydrogen bonding.
(Refer to Image)
Intramolecular Hydrogen bonding

1095760_1191959_ans_447c040b22d141d5b217344708fa67b2.PNG

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