Which is the best method of preparing $2^{o}$ amine?

C H C l_{3} + N H_{3} ⟶

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C H_{3} C l K C N ⟶ S n / H C L ⟶

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C H_{3} C l A g C N ⟶ L i A I H_{4} ⟶

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C H_{3} N H_{2} C H C l_{3} / K O H ⟶ S n / H C L ⟶

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Solution

The correct option is D $C H_{3} N H_{2} C H C l_{3} / K O H ⟶ S n / H C L ⟶$
$C H_{3} - N H_{2} C H C l_{3} - --- \to K O H C H_{3} - \oplus N \equiv C^{⊝} S n / H C l - ---- \to C H_{3} - N H - C H_{3} 2^{o} - a m i n e$

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NaCl, HCl

C H_{3} COONa

^{- 1}

^{2}

C H_{3} COOH

C {\oplus H}_{3}

\oplus N H_{4}

H_{3} O^{\oplus}

{C O}_{2}

{S O}_{3}

C {⊖ H}_{3}

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